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Intensities in Raman Spectra. IV. Intensity Measurements for Some Chloromethanes

D. A. Long, D. C. Milner and A. G. Thomas
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences
Vol. 237, No. 1209 (Oct. 9, 1956), pp. 197-211
Published by: Royal Society
Stable URL: http://www.jstor.org/stable/100073
Page Count: 15
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Since scans are not currently available to screen readers, please contact JSTOR User Support for access. We'll provide a PDF copy for your screen reader.
Intensities in Raman Spectra. IV. Intensity Measurements for Some Chloromethanes
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Abstract

The calculation of derivations of the invariants of the molecular polarizabilities from experimentally measured Raman intensities is critically discussed. Intensity formulae of an earlier paper are reviewed and a simplification introduced. Intensity measurements for the compounds CCl4, CHCl3 and CH2Cl2 are tabulated and discussed in relation to a bond polarizability theory. A modification of the simple theory is investigated.

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