Access

You are not currently logged in.

Access your personal account or get JSTOR access through your library or other institution:

login

Log in to your personal account or through your institution.

Xenon as a Nucleophile in Gas-Phase Displacement Reactions: Formation of the Methyl Xenonium Ion

David Holtz and J. L. Beauchamp
Science
New Series, Vol. 173, No. 4003 (Sep. 24, 1971), pp. 1237-1238
Stable URL: http://www.jstor.org/stable/1731972
Page Count: 2
  • More info
  • Cite this Item
Preview not available
Preview not available

Abstract

Xenon undergoes reaction with protonated methyl fluoride in the gas phase to form abundant quantities of the stable methyl xenonium ion, CH$_{3}$Xe$^{+}$. Estimated values for the xenon-carbon and krypton-carbon bond strengths in the rare gas-methyl molecular ions are 43 ± 8 and 21 ± 15 kilocalories per mole, respectively.

Page Thumbnails

  • Thumbnail: Page 
1237
    1237
  • Thumbnail: Page 
1238
    1238