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Intercalation of Metallocenes in the Layered Transition-Metal Dichalcogenides

Martin B. Dines
Science
New Series, Vol. 188, No. 4194 (Jun. 20, 1975), pp. 1210-1211
Stable URL: http://www.jstor.org/stable/1740399
Page Count: 2
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Abstract

Novel intercalation complexes of many of the layered transition-metal dichalcogenides incorporating the metallocenes of cobalt and chromium have been prepared. Evidence is presented indicating a configuration in which the five-membered rings of the metallocene guest are situated perpendicular to the slabs of the dichalcogenide host. In the complexes the metallocenes apparently behave as pseudo-alkali metals, transferring an electron to the chalcogenide.

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