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The Chemistry of Terpenes: XXII. Some Tricylic Systems Derived from (+)-Car-3-Ene

D. A. Baines, W. Cocker, D. H. Grayson, P. H. Ladwa and N. W. A. Geraghty
Proceedings of the Royal Irish Academy. Section B: Biological, Geological, and Chemical Science
Vol. 77 (1977), pp. 323-330
Published by: Royal Irish Academy
Stable URL: http://www.jstor.org/stable/20494293
Page Count: 9
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The Chemistry of Terpenes: XXII. Some Tricylic Systems Derived from (+)-Car-3-Ene
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Abstract

Diazoacetic ester adds to the α-face of (+)-car-3-ene giving epimeric tricyclic esters whose configurations have been identified. The corresponding alcohols and their acetates respectively undergo acid-catalysed and thermal rearrangement giving isomeric bicyclic dienes. From the acetates a p-menthadiene derivative is also obtained.

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