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Gas-Phase Multiply Charged Anions

Markus K. Scheller, Robert N. Compton and Lorenz S. Cederbaum
Science
New Series, Vol. 270, No. 5239 (Nov. 17, 1995), pp. 1160-1166
Stable URL: http://www.jstor.org/stable/2889213
Page Count: 7
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Gas-Phase Multiply Charged Anions
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Abstract

Singly charged negative ions in the gas phase have attracted considerable experimental and theoretical attention over the past decades. However, the existence of free doubly or multiply charged negative ions, in particular those of small systems, has remained a curiosity and a matter of some controversy. Recent experimental and quantum mechanical studies show that multiply charged negative ions of small molecules and clusters can exist as isolated entities.

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