Access

You are not currently logged in.

Access your personal account or get JSTOR access through your library or other institution:

login

Log in to your personal account or through your institution.

If You Use a Screen Reader

This content is available through Read Online (Free) program, which relies on page scans. Since scans are not currently available to screen readers, please contact JSTOR User Support for access. We'll provide a PDF copy for your screen reader.

Vibrational Relaxation of Nitric Oxide and Carbon Monoxide, Studied by Kinetic Spectroscopy

N. Basco, A. B. Callear and R. G. W. Norrish
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences
Vol. 269, No. 1337 (Sep. 11, 1962), pp. 180-187
Published by: Royal Society
Stable URL: http://www.jstor.org/stable/2992697
Page Count: 10
  • Read Online (Free)
  • Cite this Item
Since scans are not currently available to screen readers, please contact JSTOR User Support for access. We'll provide a PDF copy for your screen reader.
Vibrational Relaxation of Nitric Oxide and Carbon Monoxide, Studied by Kinetic Spectroscopy
Preview not available

Abstract

Vibrationally excited carbon monoxide was produced by flashing mixtures of nitric oxide, carbon monoxide and nitrogen. The rate of formation and decay of the vibrationally excited molecules was interpreted by means of the processes: NO (X2 II, v = 0) + hν → NO (A2 Σ+, v = 0. 1, 2), NO (A2 Σ+, v = 0, 1, 2) + M →→ NO (X2 II, v = 1) + M, NO (A2 Σ+, v = 0, 1, 2) →→ NO (X2 II, v = 1) + hν, $\mathrm{NO} (X^2 II, v = 1) + \mathrm{CO}X^1 \Sigma^+ (v = 0) \rightleftarrows \mathrm{NO} (X^2 II, v = 0) + \mathrm{CO} (X^1 \Sigma^+, v = 1),$ $\mathrm{CO} (X^1 \Sigma^+, v = 1) + \mathrm{N}_2 X^1 \Sigma^+_g (v = 0) \rightleftarrows \mathrm{CO} (X^1 \Sigma^+, v = 0) + \mathrm{N}_2(X^1 \Sigma^+_g, v = 1),$ NO (X2 II, v = 1) + NOX2 II(v = 0) → 2NO (X2 II, v = 0).

Page Thumbnails

  • Thumbnail: Page 
180
    180
  • Thumbnail: Page 
181
    181
  • Thumbnail: Page 
182
    182
  • Thumbnail: Page 
[unnumbered]
    [unnumbered]
  • Thumbnail: Page 
[unnumbered]
    [unnumbered]
  • Thumbnail: Page 
183
    183
  • Thumbnail: Page 
184
    184
  • Thumbnail: Page 
185
    185
  • Thumbnail: Page 
186
    186
  • Thumbnail: Page 
187
    187