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Direct Measurement of the Preferred Sense of NO Rotation after Collision with Argon
K. Thomas Lorenz, David W. Chandler, James W. Barr, Wenwu Chen, George L. Barnes and Joseph I. Cline
New Series, Vol. 293, No. 5537 (Sep. 14, 2001), pp. 2063-2066
Published by: American Association for the Advancement of Science
Stable URL: http://www.jstor.org/stable/3084553
Page Count: 4
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The preferred sense of product molecule rotation (clockwise or counterclockwise) in a bimolecular collision system has been measured. Rotationally inelastic collisions of nitric oxide (NO) molecules with Ar atoms were studied by combining crossed molecular beams, circularly polarized resonant multiphoton ionization probing, and velocity-mapped ion imaging detection. The observed sense of NO product rotation varies with deflection angle and is a strong function of the NO final rotational state. The largest preferences for sense of rotation are observed at the highest kinematically allowed product rotational states; for lower rotational states, the variation with deflection angle becomes oscillatory. Quantum calculations on the most recently reported NO-Ar potential give good agreement with the observed oscillation patterns in the sense of rotation.
Science © 2001 American Association for the Advancement of Science