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A Note on Dipolarity-Polarizability Effects for Aromatic Solvents
Orland W. Kolling
Transactions of the Kansas Academy of Science (1903-)
Vol. 98, No. 3/4 (Dec., 1995), pp. 113-117
Published by: Kansas Academy of Science
Stable URL: http://www.jstor.org/stable/3628235
Page Count: 5
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For aromatic polar and apolar solvents, the solvent dipolarities (π *) from linear solvation free energy relationships (LSFE) can be correlated to their respective molecular dipole moments. The added secondary polarizability effects observed for these solvents usually have been rationalized in terms of the Onsager function in index of refraction. However, the interpretation of such secondary effects can be clarified by using a semiquantitative molecular orbital treatment of molecular polarizability-hyperpolarizabilities for the simple alkylbenzenes and halobenzenes.
Transactions of the Kansas Academy of Science (1903-) © 1995 Kansas Academy of Science