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Gas-Phase Electron Paramagnetic Resonance Spectrum and Dipole Moment of NF(1Δ )
A. H. Curran, R. G. Macdonald, A. J. Stone and B. A. Thrush
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences
Vol. 332, No. 1590 (Mar. 27, 1973), pp. 355-363
Published by: Royal Society
Stable URL: http://www.jstor.org/stable/78328
Page Count: 9
You can always find the topics here!Topics: Magnetic fields, Electric fields, Nitrogen, Magnetism, Molecules, Magnets, Rotational spectra, Electrons, Atoms, Nuclear interactions
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The gas-phase paramagnetic resonance spectrum of NF in the J = 2 rotational level of the 1Δ state has been studied, and the dipole moment in this state is found to be 0.37 ± 0.60D. The rotational constant previously determined from the electronic spectrum is shown to be consistent with the electron resonance results, and the 14N quadrupole coupling constant e2qQ is 4.1± 0.2 MHz. The hyperfine coupling constants of the 14N and 19F nuclei are +109.92± 0.14 and+758.06± 0.23 MHz respectively.
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences © 1973 Royal Society