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Forbidden Transitions in the Palladium I Spectrum

A. G. Shenstone
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences
Vol. 219, No. 1139 (Oct. 7, 1953), pp. 419-425
Published by: Royal Society
Stable URL: http://www.jstor.org/stable/99244
Page Count: 8
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Forbidden Transitions in the Palladium I Spectrum
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Abstract

A new examination of the palladium are spectrum has resulted in the discovery of a type of forbidden transition which has not previously been observed. The level K1, in particular, is shown to give many more forbidden than allowed lines. The explanation is in the theory of 'forced' dipole radiation, a type of Stark effect which is due to the interionic fields in the arc. Additions to the analysis of Pd I are also given.

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