Access

You are not currently logged in.

Access your personal account or get JSTOR access through your library or other institution:

login

Log in to your personal account or through your institution.

If You Use a Screen Reader

This content is available through Read Online (Free) program, which relies on page scans. Since scans are not currently available to screen readers, please contact JSTOR User Support for access. We'll provide a PDF copy for your screen reader.

The Crystal and Molecular Structure of Perylene

D. M. Donaldson, J. M. Robertson and J. G. White
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences
Vol. 220, No. 1142 (Dec. 8, 1953), pp. 311-321
Published by: Royal Society
Stable URL: http://www.jstor.org/stable/99329
Page Count: 11
  • Read Online (Free)
  • Cite this Item
Since scans are not currently available to screen readers, please contact JSTOR User Support for access. We'll provide a PDF copy for your screen reader.
The Crystal and Molecular Structure of Perylene
Preview not available

Abstract

Perylene, C20H12, crystallizes in the monoclinic system, space group P 21/a, with four molecules in the unit cell. The structure resembles that of pyrene and 1: 12-benzperylene, and has been determined by trial and error and Fourier series methods. In the principal electron-density projection eleven of the twenty carbon atoms in the molecule can be resolved, and the positions of the others can be estimated. The accuracy is not very high, but after averaging in accordance with the expected molecular symmetry the bond lengths can be determined to within about ± 0· 04 Å. The results agree with molecular orbital calculations, and in particular it is found that a pair of unusually long bonds (∼ 1· 50 Å) connect the two naphthalene nuclei. The structure of the molecule is discussed in relation to other physical and chemical evidence. The carbon skeleton is at least approximately planar, but the 1, 12 and 6, 7 hydrogen atoms may deviate from the mean molecular plane.

Page Thumbnails

  • Thumbnail: Page 
311
    311
  • Thumbnail: Page 
312
    312
  • Thumbnail: Page 
313
    313
  • Thumbnail: Page 
314
    314
  • Thumbnail: Page 
315
    315
  • Thumbnail: Page 
316
    316
  • Thumbnail: Page 
317
    317
  • Thumbnail: Page 
318
    318
  • Thumbnail: Page 
319
    319
  • Thumbnail: Page 
320
    320
  • Thumbnail: Page 
321
    321